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Flashcards · 9702 · A Level Topic 14
Temperature (A Level) flashcards
16 cards on A Level Topic 14, subtopics 14.1 to 14.3. Pick a subtopic or study them all.
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14.1 Thermal equilibrium
- In which direction is thermal energy transferred?
- From a region of higher temperature to a region of lower temperature, not from higher to lower internal energy.
- Thermal equilibrium
- Two bodies are in thermal equilibrium when there is no net transfer of thermal energy between them. This happens when they are at the same temperature.
- Why does a thermometer read the temperature of the body it touches?
- Once thermal equilibrium is reached there is no net energy flow, so the thermometer is at the same temperature as the body.
- Are temperature and thermal energy the same thing?
- No. A large bath of warm water can hold far more thermal energy than a cup of boiling water, yet energy flows from the cup to the bath if they are in contact.
14.2 Temperature scales
- Physical properties that vary with temperature and can be used to measure it
- For example: the density of a liquid, the volume of a gas at constant pressure, the resistance of a metal, the e.m.f. of a thermocouple.
- What is special about the thermodynamic (Kelvin) scale?
- It is an absolute scale that does not depend on the property of any particular substance. Two empirical thermometers can agree at the fixed points yet disagree between them.
- Absolute zero, 0 K
- The temperature at which all substances have minimum internal energy.
- Converting between kelvin and degrees Celsius
- T/K = θ/°C + 273.15.
- Is a temperature change of 15 °C the same as a change of 15 K?
- Yes. Intervals are the same size on both scales; only absolute temperatures differ (by 273.15). T must still be in kelvin in pV = nRT.
- Triple point of water, 273.16 K
- The unique temperature and pressure at which ice, water and water vapour coexist in equilibrium.
14.3 Specific heat capacity and specific latent heat
- Specific heat capacity
- The energy needed per unit mass to raise the temperature by one degree (1 K), without a change of state. Q = mcΔθ. Unit J kg⁻¹ K⁻¹.
- How much energy heats 500 g of water (c = 4200 J kg⁻¹ K⁻¹) from 20 °C to 80 °C?
- Q = mcΔθ = 0.500 × 4200 × 60 = 126 000 J.
- Specific latent heat
- The energy needed per unit mass to change the state of a substance without a change of temperature. Q = mL. Unit J kg⁻¹.
- Specific latent heat of fusion vs of vaporisation
- Fusion: solid ↔ liquid (melting or freezing). Vaporisation: liquid ↔ gas (boiling or condensing).
- Why is the specific latent heat of vaporisation larger than that of fusion?
- Boiling must separate the molecules completely, overcoming the intermolecular forces, and also do work pushing back the atmosphere. Melting only loosens the forces.
- Why is the temperature constant on a heating or cooling curve during a change of state?
- The energy transferred changes the potential energy of the molecules (latent heat), not their mean kinetic energy.