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Marlbridge

Flashcards · 5070 · Topic 9

Metals flashcards

28 cards on Topic 9, subtopics 9.1 to 9.6. Pick a subtopic or study them all.

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9.1 Properties of metals

General physical properties of metals
Good conductors of heat and electricity, malleable, ductile, and usually high melting and boiling points.
General physical properties of non-metals
Poor conductors of heat and electricity, brittle when solid, and usually low melting and boiling points.
metal + dilute acid → metal + oxygen →
salt + hydrogen metal oxide

9.2 Uses of metals

Aluminium: two uses and the property behind each
Aircraft parts — low density. Food containers — resistance to corrosion.
Copper: a use and the properties behind it
Electrical wiring — good electrical conductor and ductile.
Aluminium in overhead electrical cables: which properties?
Low density and good electrical conductivity.
Copper in electrical wiring: which properties, and what does ductile mean?
Good electrical conductivity and ductility. Ductile means it can be drawn out into wires.

9.3 Alloys and their properties

Alloy
A mixture of a metal with other elements.
What is brass made from?
Copper and zinc.
Stainless steel: composition and a use
Iron mixed with chromium, nickel and carbon. Used for cutlery, because it is hard and resists corrosion.
How do the hardness and strength of an alloy compare with the pure metal?
Alloys can be harder and stronger than the pure metals.
Explain why an alloy is harder than the pure metal
The different-sized atoms disrupt the regular layers, so the layers cannot slide over each other as easily.

9.4 Reactivity series

The reactivity series (most to least reactive), with carbon and hydrogen
Potassium, sodium, calcium, magnesium, aluminium, (carbon), zinc, iron, (hydrogen), copper, silver, gold.
Which metals react with cold water, and which only with steam?
Cold water: potassium, sodium, calcium. Steam: magnesium (very slow with cold water), zinc and iron.
Will magnesium displace zinc from zinc sulfate solution?
Yes. Magnesium is more reactive than zinc, so it gives up electrons more readily and displaces it.
Why does aluminium seem unreactive?
It is covered by a thin, protective layer of aluminium oxide.

9.5 Corrosion of metals

What two things are needed for iron to rust?
Water and oxygen.
Rust
Hydrated iron(III) oxide.
Barrier methods of rust prevention
Painting, greasing (oiling) and coating with plastic — they keep out water and oxygen.
Sacrificial protection
Attaching a more reactive metal (such as zinc or magnesium) to iron. It corrodes instead of the iron.
Galvanising, and why it beats tin plating
Coating iron with zinc. It is a barrier and also sacrificial, so iron is still protected if scratched. Tin is less reactive than iron, so scratched tin plate rusts faster.

9.6 Extraction of metals

How a metal’s position in the reactivity series decides its extraction method
More reactive than carbon: electrolysis. Less reactive than carbon: reduction by heating with carbon.
Raw materials of the blast furnace
Hematite (iron ore), coke (carbon), limestone and hot air.
What reduces iron(III) oxide in the blast furnace?
Carbon monoxide.
Main ore of aluminium, and how aluminium is extracted
Bauxite. Aluminium is extracted by electrolysis.
Equation for the reduction of iron(III) oxide in the blast furnace
Fe₂O₃ + 3CO → 2Fe + 3CO₂
How limestone removes impurities in the blast furnace
CaCO₃ → CaO + CO₂, then CaO + SiO₂ → CaSiO₃ (slag).
Role of cryolite in aluminium extraction
Aluminium oxide is dissolved in molten cryolite, which lowers the operating temperature and improves conductivity.