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AP® Chemistry · Unit 1 · Topic 1.2

Mass Spectra of Elements: Topic Checklist (Chemistry 1.2)

Specific “I can…” statements for mass spectra of elements and average atomic mass, each linked to the guide section and practice question that tests it.

Work through the list without notes. If you cannot do a statement, follow its link, then come back. Guide = study guide; Practice = practice questions.

Understanding

  • I can explain what isotopes are and why isotopes of one element have the same chemistry. (Guide: “Isotopes”)
  • I can describe the main stages of a mass spectrometer (background) and explain why m/z equals the isotope mass for a +1 ion. (Guide: “What a mass spectrometer does”; Practice Q7)
  • I can say what the number, position and height of the peaks in a one-element spectrum tell me. (Guide: “Reading a mass spectrum”; Practice Q1)
  • I can explain why, for an element with several isotopes, no single atom has the average atomic mass. (Guide: “Common misconceptions”; Practice Q6)
  • I can state which kinds of spectra are outside this topic’s assessment (mixtures, molecules, ions that are not +1). (Guide: “What you will and will not be asked”)

Calculation

  • I can calculate an average atomic mass from isotope masses and percentage abundances. (Guide: Worked example 1; Practice Q4)
  • I can convert peak heights scaled to the tallest peak into percentage abundances, then find the average. (Guide: Worked example 2; Practice Q2, Q6)
  • I can find the abundances of two isotopes from an average atomic mass, using x and 1 − x. (Guide: Worked example 3; Practice Q5)
  • I can predict the relative height of a peak from the abundances. (Practice Q5(b))

Reasoning

  • I can check an average atomic mass: it must lie between the isotope masses, nearest the most abundant one. (Practice Q2, Q3)
  • I can identify an element by comparing a spectrum with average atomic masses. (Practice Q3)
  • I can use evidence from a spectrum to evaluate a claim about isotopes or average atomic mass. (Practice Q6, Q7)
  • I can explain why a sample with an unusual isotope mix has a different average atomic mass from the periodic-table value. (Practice Q7)

All ticked? Move on to Topic 1.3, Elemental Composition of Pure Substances, or return to the course roadmap.

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