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AP® Chemistry · Unit 2 · Topic 2.3

Structure of Ionic Solids: Topic Checklist (Chemistry 2.3)

Specific “I can…” statements for the structure of ionic solids, each linked to the guide section and practice question that shows whether you can really do it.

Work through the list without notes. If you cannot do a statement, follow its link, then come back. Guide = study guide; Practice = practice questions.

Understanding

  • I can describe an ionic solid as a repeating three-dimensional array of cations and anions, and explain why it contains no molecules. (Guide: “What an ionic solid really is”; Practice Q1)
  • I can explain why each ion is surrounded by ions of the opposite charge, in terms of attraction and repulsion. (Guide; Practice Q5)
  • I can explain what a formula such as CaF₂ tells me about an ionic solid, and what it does not tell me. (Guide; Revision notes)
  • I can explain why a cation is smaller than its atom and an anion is larger than its atom, and why isoelectronic ions differ in size. (Guide: “Ion sizes you can use”; Practice Q6)

Skills

  • I can draw a particulate model of an ionic solid with alternating charges, sensible relative sizes, the formula ratio and labelled charges. (Guide: Figure 1; Practice Q5)
  • I can find an error in someone else’s particulate model and correct it. (Guide: Worked example 1; Practice Q1)
  • I can calculate the distance between ion centres from ionic radii and use |q₊q₋| / d to compare ionic solids. (Guide: Worked example 2; Practice Q6)
  • I can rank ionic solids by strength of attraction, considering charge first and then ion size. (Practice Q2, Q3)

Reasoning

  • I can explain why ionic solids are brittle, using what happens to the charges when a layer slides. (Guide: Figure 2; Practice Q4)
  • I can explain why an ionic solid conducts electricity only when it is molten or dissolved. (Practice Q7)
  • I can predict which of two ionic solids has the higher melting point and justify it with Coulomb’s law. (Guide: Worked example 2; Practice Q6)

All ticked? Move on to Topic 2.4, Structure of Metals and Alloys, or return to the course roadmap.

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