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AP® Chemistry · Unit 2 · Topic 2.6

Resonance and Formal Charge: Topic Checklist (Chemistry 2.6)

Specific “I can…” statements for resonance and formal charge, each linked to the guide section and practice question that shows whether you can really do it.

Work through the list without notes. If you cannot do a statement, follow its link, then come back. Guide = study guide; Practice = practice questions.

Understanding

  • I can explain what a resonance hybrid is, and why the molecule does not switch between its resonance structures. (Guide: “The resonance hybrid”)
  • I can explain why resonance is needed to predict bond lengths, bond energies and where the charge is. (Guide: Worked example 1; Practice Q5)
  • I can explain what formal charge assumes, and why it is not the real charge on an atom. (Guide: “Formal charge”)
  • I can explain why species with an odd number of valence electrons show a limitation of the Lewis model. (Guide: Worked example 3; Practice Q7)

Skills

  • I can draw all the equivalent resonance structures of a molecule or ion. (Guide: Worked example 1; Practice Q4, Q5)
  • I can calculate the average bond order from resonance structures, including cases such as nitrate where it is not 1.5. (Practice Q2)
  • I can calculate the formal charge on every atom and check that the sum equals the overall charge. (Practice Q1, Q6)
  • I can rank bond lengths using bond orders from Lewis diagrams. (Practice Q3, Q5)

Reasoning

  • I can use formal charge to choose between two possible skeletons. (Guide: Worked example 2; Practice Q6)
  • I can rank nonequivalent resonance structures using the octet rule, the size of the formal charges and electronegativity. (Guide: Worked example 2; Practice Q4)
  • I can explain what to do when the octet rule and formal charge favour different diagrams. (Guide: “When the octet rule and formal charge disagree”)
  • I can evaluate a claim about a molecule’s structure using resonance or formal charge as evidence. (Practice Q5, Q7)

All ticked? Move on to Topic 2.7, VSEPR and Hybridization, or return to the course roadmap.

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