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AP® Chemistry · Unit 4 · Topic 4.1

Introduction for Reactions: Revision Notes (Chemistry 4.1)

One-page recap of physical and chemical changes, the four common signs of a reaction, the physical changes that mimic them, and how to test for a new substance.

Short on time? This page is the recap. For explanations and worked examples, use the full study guide.

Recap

  • A physical change alters properties such as state, shape or mixing, but every substance keeps its composition.
  • Common physical changes: phase changes (melting, boiling, sublimation and their reverses) and making or separating mixtures (dissolving, filtering, distilling).
  • A chemical change forms new substances. Atoms are kept but rearranged into new combinations.
  • Four common signs of a chemical change: heat or light, a gas, a precipitate, a colour change.

Key relationships

Sign Points to a reaction when… Can be faked by…
Heat or light energy is released as a new substance forms dissolving NaOH (hot) or NH₄NO₃ (cold)
Gas the gas is a new substance (e.g. CO₂ turns limewater cloudy) boiling; dissolved gas escaping
Precipitate two solutions mix and an insoluble product forms crystals forming as a saturated solution cools
Colour change a new colour appears dilution making a colour paler

Assumptions behind the evidence

  • One observation is a clue. The deciding question is: has a substance with a different composition formed?
  • A reaction can give no visible sign (strong acid + strong base: only the temperature rises).
  • Mass is conserved in a closed container. An open container loses mass only if a gas escapes.

Mistakes to avoid

  1. “Temperature changed, so it reacted.” Dissolving and phase changes also transfer energy.
  2. Calling dilution a colour change. A paler shade of the same colour is not a new substance.
  3. Claim with no reasoning. Link the evidence to a new substance forming.
  4. Using reversibility as the test. Composition decides, not how easy the change is to undo.
  5. Saying atoms are lost when an open flask gets lighter. The gas has left the flask.

Quick self-check

  1. Is distilling sea water physical or chemical? (Physical: it separates a mixture.)
  2. Name a physical change that produces bubbles. (Boiling, or gas escaping from fizzy water.)
  3. A sealed bag containing baking soda and vinegar weighs 64.30 g before mixing. What does it weigh afterwards? (64.30 g: no gas can escape. Ignore the tiny buoyancy effect as the bag swells.)
  4. Why is a precipitate good evidence? (The solid is a substance that was not present in either solution.)

Next: practice questions.

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