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AP® Chemistry · Unit 6 · Topic 6.7

Bond Enthalpies: Topic Checklist (Chemistry 6.7)

Specific “I can…” statements for bond enthalpies, each linked to the guide section and practice question that shows whether you can really do it.

Work through the list without notes. If you cannot do a statement, follow its link, then come back. Guide = study guide; Practice = practice questions.

Understanding

  • I can explain why breaking a bond needs energy and forming the same bond releases the same amount. (Guide: “Where the energy of a reaction comes from”; Practice Q1)
  • I can define bond enthalpy and say why it is always a positive number. (Guide: “Bond enthalpy: an average value”)
  • I can explain why a table value is an average, and why that makes the answer an estimate. (Guide; Practice Q4)
  • I can explain why a fuel releases energy without saying that breaking bonds releases energy. (Practice Q7)

Calculation

  • I can draw Lewis structures and list every bond broken and formed, multiplied by the coefficients. (Guide: “Counting bonds without mistakes”; Practice Q3, Q5)
  • I can estimate ΔH as Σ(bonds broken) − Σ(bonds formed), with the correct sign. (Guide: Worked examples 1 and 2; Practice Q2)
  • I can use the correct values for double and triple bonds, including O=O, N≡N and the C=O bonds in CO₂. (Practice Q3, Q5)
  • I can cancel bonds that do not change and get the same answer. (Guide: Worked example 2)
  • I can scale ΔH to a given mass of reactant. (Practice Q5)
  • I can work backwards from a known ΔH to estimate one unknown bond enthalpy. (Guide: Worked example 3; Practice Q6)

Reasoning

  • I can decide whether a reaction is exothermic or endothermic by comparing the energy needed to break bonds with the energy released forming bonds. (Guide: Worked example 1; Practice Q1, Q7)
  • I can represent the method as a step diagram: up to separate atoms, then down to products. (Guide: Figure 1; Practice Q7)
  • I can give two reasons a bond-enthalpy estimate differs from a measured value: averaging and non-gaseous substances. (Guide: “Why the answer is only an estimate”; Practice Q4, Q7)

All ticked? Move on to Topic 6.8, Enthalpy of Formation, or return to the course roadmap.

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