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AP® Chemistry · Unit 6 · Topic 6.8

Enthalpy of Formation: Topic Checklist (Chemistry 6.8)

Specific “I can…” statements for enthalpies of formation, each linked to the guide section and practice question that shows whether you can really do it.

Work through the list without notes. If you cannot do a statement, follow its link, then come back. Guide = study guide; Practice = practice questions.

Understanding

  • I can define the standard enthalpy of formation, including “1 mol” and “elements in their standard states”. (Guide: “What a standard enthalpy of formation is”)
  • I can write the formation equation for a compound, using fractions where needed. (Practice Q2)
  • I can explain why an element in its standard state has ΔH°f = 0, and name forms of elements that are not zero. (Guide; Practice Q1, Q6)
  • I can explain why the formula works, using a detour through the elements. (Guide: Figure 1)

Calculation

  • I can calculate ΔH° as ΣnΔH°f(products) − ΣnΔH°f(reactants), with every coefficient applied. (Guide: Worked examples 1 and 2; Practice Q3, Q4)
  • I can choose the right value for the state shown, such as H₂O(l) or H₂O(g). (Guide: Worked example 2; Practice Q5)
  • I can scale ΔH° to a given mass or amount of one substance. (Practice Q5)
  • I can calculate ΔH° for a physical change, such as vaporising water or methanol. (Guide: “Physical processes too”; Practice Q6)
  • I can work backwards from a known ΔH° to find one unknown ΔH°f. (Guide: Worked example 3; Practice Q6)

Reasoning

  • I can use the sign of ΔH° to say whether a process is exothermic or endothermic. (Guide: Worked example 1; Practice Q4)
  • I can describe an energy diagram with the elements at 0 and explain why a reaction between substances with positive ΔH°f can still be exothermic. (Practice Q7)
  • I can explain why formation enthalpies give more accurate reaction enthalpies than bond enthalpies. (Guide: “Why we need a table of formation enthalpies”)

All ticked? Move on to Topic 6.9, Hess’s Law, or return to the course roadmap.

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