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AP® Chemistry · Unit 7 · Topic 7.3

Reaction Quotient and Equilibrium Constant: Topic Checklist (Chemistry 7.3)

Specific “I can…” statements for writing Q and K expressions, each linked to the guide section and practice question that shows whether you can really do it.

Work through the list without notes. If you cannot do a statement, follow its link, then come back. Guide = study guide; Practice = practice questions.

Understanding

  • I can explain the difference between Q, which describes a mixture at any moment, and K, the value Q reaches at equilibrium. (Guide: “Q at any moment, K at equilibrium”; Practice Q5)
  • I can state that at equilibrium Qc = Kc and Qp = Kp, and that Q moves towards K as a reaction runs. (Guide: Figure 1; Practice Q5(d))
  • I can explain that Kc uses concentrations and Kp uses partial pressures, so their values usually differ. (Guide: “Gases: Qp and Kp”; Practice Q5(b))
  • I can explain why pure solids and pure liquids are left out of Q and K. (Guide: “What to leave out”; Practice Q7)

Skills

  • I can write Kc for a reaction with gases, with each concentration raised to its coefficient. (Guide: Worked example 1; Practice Q1)
  • I can write Kp for a heterogeneous reaction, leaving out the solids. (Guide: Worked example 3; Practice Q2, Q7)
  • I can write Kc for a reaction in water, leaving out H₂O(l) but keeping H₂O(g) when it appears. (Practice Q1, Q3)
  • I can substitute concentrations or partial pressures into Q and calculate its value. (Guide: Worked example 2; Practice Q4, Q5(c))
  • I can plot Q against time with labelled axes and an even scale, and read K from the flat part. (Guide: Figure 1; Practice Q6)

Reasoning

  • I can decide whether a mixture is at equilibrium by comparing Q with K. (Guide: Worked examples 2 and 3; Practice Q5(d))
  • I can explain why two mixtures that start differently at the same temperature end with the same value of Q. (Practice Q6(e))
  • I can explain why adding more of a solid does not change Q. (Guide: Worked example 3; Practice Q7(b))

All ticked? Move on to Topic 7.4, Calculating the Equilibrium Constant, or return to the course roadmap.

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