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AP® Chemistry · Unit 7 · Topic 7.4

Calculating the Equilibrium Constant: Topic Checklist (Chemistry 7.4)

Specific “I can…” statements for calculating Kc and Kp from equilibrium data, each linked to the guide section and practice question that tests it.

Work through the list without notes. If you cannot do a statement, follow its link, then come back. Guide = study guide; Practice = practice questions.

Understanding

  • I can explain how experimental data show that a system has reached equilibrium. (Guide: Figure 1; Practice Q5(e))
  • I can explain why only equilibrium values, not starting values, go into K. (Guide: “Common misconceptions”; Practice Q3)
  • I can explain why experiments at the same temperature give the same K even when their concentrations differ. (Practice Q7(b))

Calculation

  • I can calculate Kc from a set of equilibrium concentrations. (Guide: Worked example 1(a); Practice Q1)
  • I can calculate Kp from equilibrium partial pressures, leaving out any solid. (Guide: Worked example 1(b); Practice Q2)
  • I can convert moles to mol L⁻¹ before using Kc. (Guide: Worked example 2)
  • I can build an ICE table from starting amounts and one measured equilibrium value, using the coefficients for the change row. (Guide: Worked example 2; Practice Q3, Q5)
  • I can allow for dilution when two solutions are mixed. (Practice Q5(b))
  • I can turn a total pressure into partial pressures using the mole ratio of the gases. (Guide: Worked example 3; Practice Q6)
  • I can use a known K to find one missing equilibrium concentration. (Practice Q7(c))

Reasoning

  • I can explain, using the powers in the expression, how one equilibrium concentration must change when another changes at constant K. (Guide: “Reading K as a relationship”; Practice Q4)
  • I can spot a calculation error when two experiments at the same temperature give very different K values. (Guide: “Reading K as a relationship”; Practice Q7)

All ticked? Move on to Topic 7.5, Magnitude of the Equilibrium Constant, or return to the course roadmap.

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