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AP® Chemistry · Unit 7 · Topic 7.5

Magnitude of the Equilibrium Constant: Topic Checklist (Chemistry 7.5)

Specific “I can…” statements for reading the size of K, each linked to the guide section and practice question that shows whether you can really do it.

Work through the list without notes. If you cannot do a statement, follow its link, then come back. Guide = study guide; Practice = practice questions.

Understanding

  • I can explain, using the shape of the K expression, why a very large K means the equilibrium mixture is mostly products. (Guide: “What the size of K tells you”; Practice Q1)
  • I can explain why a very small K means the reaction barely proceeds, and why the product concentration is still not zero. (Guide: Worked example 2; Practice Q2)
  • I can say what “essentially to completion” means and why it is different from “complete”. (Guide: Worked example 1; Practice Q5)
  • I can explain why K tells me nothing about how fast equilibrium is reached, and what a catalyst does and does not change. (Guide: “K tells you where, not how fast”; Practice Q6)

Calculation

  • I can read K from a particle diagram for a 1 : 1 reaction, and draw a diagram that matches a given K. (Guide: Figure 1; Practice Q3)
  • I can use [A] + [B] = total with [B]/[A] = K to find the composition of an A ⇌ B mixture and the percentage converted. (Guide: Worked example 1; Practice Q4)
  • I can find the trace concentration of a product (or reactant) when K is very small (or very large). (Guide: Worked example 2; Practice Q5)
  • I can show that a given set of concentrations is an equilibrium mixture by substituting into the K expression. (Practice Q7)

Reasoning

  • I can use the value of K, with a short calculation, to justify or reject a claim about an equilibrium mixture. (Practice Q5, Q7)
  • I can explain why K values are only directly comparable as ratios when the expressions have the same shape, and why K must be quoted with a temperature. (Guide: “Comparing K values fairly”; Practice Q7)

All ticked? Move on to Topic 7.6, Properties of the Equilibrium Constant, or return to the course roadmap.

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