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AP® Chemistry · Unit 7 · Topic 7.9

Introduction to Le Châtelier's Principle: Topic Checklist (Chemistry 7.9)

Specific “I can…” statements for Le Châtelier's principle, each linked to the guide section and practice question that shows whether you can really do it.

Work through the list without notes. If you cannot do a statement, follow its link, then come back. Guide = study guide; Practice = practice questions.

Understanding

  • I can state Le Châtelier’s principle and explain that the shift only partly undoes the stress. (Guide: “What Le Châtelier’s principle says”, Figure 1)
  • I can explain a shift in terms of the forward and reverse rates becoming unequal and then equal again. (Guide: “Why it works: rates”)
  • I can name the changes that cause no shift: a catalyst, extra solid or pure liquid, and an unreactive gas added at constant volume. (Guide: “Changes that cause no shift”; Practice Q1, Q6(c))
  • I can say which stress changes the value of K, and which do not. (Guide: Stress 2; Practice Q3)

Skills

  • I can predict the shift when a reactant or product is added, or removed by precipitation or reaction. (Guide: Worked example 1; Practice Q2, Q6(d))
  • I can write heat into an equation and predict the effect of heating or cooling. (Guide: Stress 2; Practice Q1, Q6(b))
  • I can count gas molecules to predict the effect of a volume change, including the case of equal numbers. (Guide: Stress 3; Practice Q4, Q6(a))
  • I can count dissolved particles, leaving out solvent water, to predict the effect of dilution. (Guide: Stress 4; Practice Q5(b))

Reasoning

  • I can predict what an observer would see: a colour change, a pH change or a temperature change. (Guide: “What you would actually see”; Practice Q3, Q5(c))
  • I can separate the instant effect of compressing a gas from the shift that follows. (Guide: Worked example 2; Practice Q4)
  • I can deduce the sign of ΔH from an observed effect of temperature. (Practice Q5(a))
  • I can evaluate a claim about adding a solid to a heterogeneous equilibrium. (Practice Q7)

All ticked? Move on to Topic 7.10, Reaction Quotient and Le Châtelier’s Principle, or return to the course roadmap.

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