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AP® Chemistry · Unit 8 · Topic 8.3

Weak Acid and Base Equilibria: Topic Checklist (Chemistry 8.3)

Specific “I can…” statements for weak acid and weak base equilibria, each linked to the guide section and practice question that shows whether you can really do it.

Work through the list without notes. If you cannot do a statement, follow its link, then come back. Guide = study guide; Practice = practice questions.

Understanding

  • I can explain why [H₃O⁺] in a weak acid solution is much smaller than the starting acid concentration. (Guide: “Weak means mostly not ionized”; Practice Q1)
  • I can rank [HA], [H₃O⁺], [A⁻] and [OH⁻] in a weak acid solution. (Guide: Figure 1; Practice Q1)
  • I can write K_a and K_b expressions, leaving water out, and say that a larger pK means a weaker acid or base. (Guide; Revision notes)
  • I can explain why K_a does not change on dilution but percent ionization rises. (Guide: “Percent ionization”; Practice Q4)

Calculation

  • I can find the pH of a weak acid from c and K_a or pK_a, and check the 5% approximation. (Guide: Worked example 1; Practice Q2)
  • I can solve the quadratic when the 5% check fails. (Practice Q6)
  • I can find the pH of a weak base, going through [OH⁻] and pOH. (Guide: Worked example 3; Practice Q5)
  • I can calculate K_a or K_b and percent ionization from a measured pH. (Guide: Worked example 2; Practice Q5)
  • I can convert between K_a and K_b, or pK_a and pK_b, for a conjugate pair. (Guide: “Linking a conjugate pair”; Practice Q3)

Reasoning

  • I can compare two weak acids at the same concentration and say which has the higher pH and which has the stronger conjugate base. (Practice Q7)
  • I can explain why the weaker acid leaves more un-ionized molecules in solution. (Practice Q7(c))
  • I can explain why a weak and a strong acid at the same concentration have different pH values. (Guide: Figure 1 caption; Practice Q2)

All ticked? Move on to Topic 8.4, Acid-Base Reactions and Buffers, or return to the course roadmap.

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