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Flashcards · 8463 · Topic 4

Atomic structure flashcards

27 cards on Topic 4, subtopics 4.4.1 to 4.4.4. Pick a subtopic or study them all.

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4.4.1 Atoms and isotopes

Size of an atom and of its nucleus
Atom radius: about 1 × 10⁻¹⁰ m. Nucleus radius: less than 1/10 000 of the radius of the atom.
Atomic number vs mass number
Atomic number: protons only. Mass number: protons + neutrons.
Isotope vs ion
Isotopes of an element have different numbers of neutrons. An ion has a different number of electrons from protons (so it is charged).
How many protons, neutrons and electrons are in an atom of sodium-23 (atomic number 11)?
11 protons, 23 − 11 = 12 neutrons, 11 electrons.
What happens to an electron when an atom absorbs or emits electromagnetic radiation?
Absorbs: the electron moves to a higher energy level (further from the nucleus). Emits: it moves to a lower energy level (closer to the nucleus).
Plum pudding model vs nuclear model
Plum pudding: a ball of positive charge with electrons embedded in it. Nuclear: mass and positive charge concentrated in a tiny nucleus, with electrons outside.
Alpha scattering: what each observation showed
Most went straight through: the atom is mostly empty space. Some were deflected: the centre is charged. Very few bounced back: the centre is tiny and holds most of the mass.
Who gave evidence for the neutron, and when, relative to the nuclear model?
James Chadwick, about 20 years after the nucleus became an accepted idea.

4.4.2 Atoms and nuclear radiation

Alpha, beta and gamma: what each is
Alpha: 2 protons + 2 neutrons (a helium nucleus). Beta: a high-speed electron ejected from the nucleus as a neutron turns into a proton. Gamma: electromagnetic radiation from the nucleus.
Penetration and ionising power of alpha, beta and gamma
Alpha: stopped by paper, a few cm in air, most ionising. Beta: stopped by thin aluminium. Gamma: reduced by thick lead or concrete, least ionising.
Activity
The number of decays per second of a source, in becquerel (Bq).
Count-rate
The number of decays recorded each second by a detector (for example a Geiger-Muller tube).
Effect of alpha and of beta decay on mass number and atomic number
Alpha: mass number − 4, atomic number − 2. Beta: mass number unchanged, atomic number + 1. Gamma: no change to either.
Half-life
The time it takes for the number of nuclei of the isotope in a sample to halve, or for the count-rate (or activity) to fall to half its initial level.
A source has activity 800 Bq and half-life 2 days. What is its activity after 6 days?
6 ÷ 2 = 3 half-lives: 800 → 400 → 200 → 100 Bq
Net decline as a ratio after n half-livesHigher
1 : 2ⁿ. For example, after 4 half-lives it is 1 : 16.
Contamination vs irradiation
Contamination: radioactive atoms get on or into an object, so the hazard continues. Irradiation: the object is exposed to radiation from outside; it does not become radioactive.

4.4.3 Hazards and uses of radioactive emissions and background radiation

Sources of background radiation
Natural: rocks and cosmic rays from space. Man-made: fallout from nuclear weapons testing and nuclear accidents.
Unit of radiation dose
The sievert (Sv). 1000 millisieverts (mSv) = 1 Sv.
Hazard of a source with a short half-life vs a long half-life
Short: very active at first but the activity falls quickly. Long: less intense, but stays hazardous for a long time.
What kind of source is chosen as a medical tracer, and why?
A gamma emitter, so the radiation can leave the body and reach the detector, with a half-life of hours: long enough to do the job, short enough to limit the dose.
Why is a beta source used to monitor the thickness of thin card?
Alpha would be stopped by the card; gamma would pass through almost unchanged, so small changes in thickness would not show.

4.4.4 Nuclear fission and fusion

Nuclear fission
A large unstable nucleus (such as uranium or plutonium) absorbs a neutron and splits into two smaller nuclei of roughly equal size, releasing two or three neutrons, gamma rays and energy.
Chain reaction
The neutrons released by one fission go on to cause further fissions. It is controlled in a nuclear reactor and uncontrolled in a nuclear weapon.
Nuclear fusion
Two light nuclei join to form a heavier nucleus. Some of the mass may be converted into the energy of radiation.
What usually has to happen before a uranium-235 nucleus undergoes fission?
It must absorb a neutron. Spontaneous fission is rare.
Fission vs fusion
Fission: a heavy nucleus splits. Fusion: light nuclei join.