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Flashcards · 8463 · Topic 3

Particle model of matter flashcards

19 cards on Topic 3, subtopics 4.3.1 to 4.3.3. Pick a subtopic or study them all.

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4.3.1 Changes of state and the particle model

Density equation, with units
ρ = m / V ρ in kg/m³, m in kg, V in m³.
Why is a gas much less dense than the same substance as a solid or liquid?
The same mass of particles is spread over a much bigger volume, because gas particles are far apart.
Particle arrangement and motion in a solid, a liquid and a gas
Solid: touching, regular, vibrate in place. Liquid: touching, irregular, slide past each other. Gas: far apart, random, move fast in all directions.
Why is a change of state a physical change?
Mass is conserved and, if the change is reversed, the material gets its original properties back. No new substance forms.
Required practical 5: finding the volume of an irregular solid
By displacement: measure the rise in water level in a measuring cylinder, or collect the overflow from a eureka can in a measuring cylinder.
A 0.60 kg block has a volume of 2.4 × 10⁻⁴ m³. What is its density?
ρ = 0.60 ÷ 2.4 × 10⁻⁴ = 2500 kg/m³
Sublimation
A change of state from solid straight to gas.

4.3.2 Internal energy and energy transfers

Internal energy
The total kinetic energy and potential energy of all the particles (atoms and molecules) that make up a system.
Two things heating a system can do
Raise its temperature (particles gain kinetic energy), or change its state (particles gain potential energy, temperature stays constant).
Specific latent heat
The energy needed to change the state of 1 kg of a substance with no change in temperature. E = mL (J, kg, J/kg).
Specific latent heat of fusion vs of vaporisation
Fusion: solid ↔ liquid. Vaporisation: liquid ↔ vapour.
What is happening on a flat section of a heating graph?
A change of state (melting or boiling). The energy supplied raises the internal energy, but the temperature stays constant. Use E = mL, not ΔE = mcΔθ.
How much energy melts 0.50 kg of ice at 0 °C? (L = 334 000 J/kg)
E = mL = 0.50 × 334 000 = 167 000 J

4.3.3 Particle model and pressure

What causes gas pressure?
Molecules in constant random motion collide with the container walls, producing a net force at right angles to the wall.
Temperature of a gas is related to…
The average kinetic energy of its molecules.
Why does the pressure of a gas rise when it is heated at constant volume?
The molecules move faster, so they hit the walls more often and with more force.
Why does the pressure of a gas fall when its volume increases at constant temperature?
The molecules move at the same speed but hit each unit area of the wall less often.
Gas at 200 kPa in 0.050 m³ is compressed to 0.020 m³ at constant temperature. New pressure?
p₁V₁ = p₂V₂, so p₂ = 200 × 0.050 ÷ 0.020 = 500 kPa
Why does a bicycle pump get warm when you use it?Higher
Work is done on the gas (work is the transfer of energy by a force). This increases the internal energy of the gas, so its temperature rises.