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Flashcards · 0620 · Topic 7

Acids, bases and salts flashcards

21 cards on Topic 7, subtopics 7.1 to 7.3. Pick a subtopic or study them all.

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7.1 The characteristic properties of acids and bases

pH of acidic, neutral and alkaline solutions
Acidic: below 7. Neutral: 7. Alkaline: above 7.
Colours of litmus, methyl orange and thymolphthalein in acid and in alkali
Litmus: red in acid, blue in alkali. Methyl orange: red in acid, yellow in alkali. Thymolphthalein: colourless in acid, blue in alkali.
Which ions do aqueous acids and aqueous alkalis contain?
Acids: H⁺ ions. Alkalis: OH⁻ ions.
Alkali
A soluble base. All alkalis are bases, but not all bases are alkalis.
acid + metal → acid + base → acid + carbonate →
salt + hydrogen salt + water salt + water + carbon dioxide
What is made when an alkali is warmed with an ammonium salt?
Ammonia gas (plus a salt and water).
Acid (proton definition)Extended
A proton (H⁺) donor.
Base (proton definition)Extended
A proton (H⁺) acceptor.
Strong acidExtended
Fully dissociated in water. Examples: HCl, HNO₃, H₂SO₄.
Weak acidExtended
Only partially dissociated in water. Examples: ethanoic, citric and carbonic acids.

7.2 Oxides

Acidic oxides
Oxides of non-metals, such as SO₂ and CO₂. They react with bases and alkalis.
Basic oxides
Oxides of metals, such as CuO and CaO. They react with acids.
Amphoteric oxidesExtended
Oxides that react with both acids and bases to form a salt and water. Examples: aluminium oxide, Al₂O₃, and zinc oxide, ZnO.

7.3 Preparation of salts

Making a soluble salt from an acid and an insoluble base (or carbonate or metal)
Add the solid in excess to the acid, filter off the leftover solid, then crystallise the filtrate.
When is titration used to make a salt?
When both reactants are soluble (acid + alkali), so there is no excess solid to filter off. Repeat without the indicator to get a pure salt.
Which common salts are always soluble?
All sodium, potassium and ammonium salts, and all nitrates.
Exceptions to the solubility rules for chlorides and sulfates
Chlorides: soluble except silver and lead. Sulfates: soluble except barium, calcium and lead.
Solubility of carbonates and hydroxides
Mostly insoluble, except sodium, potassium and ammonium (calcium hydroxide is partially soluble).
Hydrated and anhydrous
Hydrated: a substance chemically combined with water (e.g. CuSO₄·5H₂O). Anhydrous: containing no water.
Making an insoluble saltExtended
Precipitation: mix two solutions containing its ions, then filter, wash the precipitate with distilled water and dry it.
Water of crystallisationExtended
The water molecules chemically combined within the crystal structure of a hydrated salt.