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Flashcards · 0620 · Topic 7
Acids, bases and salts flashcards
21 cards on Topic 7, subtopics 7.1 to 7.3. Pick a subtopic or study them all.
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7.1 The characteristic properties of acids and bases
- pH of acidic, neutral and alkaline solutions
- Acidic: below 7. Neutral: 7. Alkaline: above 7.
- Colours of litmus, methyl orange and thymolphthalein in acid and in alkali
- Litmus: red in acid, blue in alkali. Methyl orange: red in acid, yellow in alkali. Thymolphthalein: colourless in acid, blue in alkali.
- Which ions do aqueous acids and aqueous alkalis contain?
- Acids: H⁺ ions. Alkalis: OH⁻ ions.
- Alkali
- A soluble base. All alkalis are bases, but not all bases are alkalis.
- acid + metal → acid + base → acid + carbonate →
- salt + hydrogen salt + water salt + water + carbon dioxide
- What is made when an alkali is warmed with an ammonium salt?
- Ammonia gas (plus a salt and water).
- Acid (proton definition)Extended
- A proton (H⁺) donor.
- Base (proton definition)Extended
- A proton (H⁺) acceptor.
- Strong acidExtended
- Fully dissociated in water. Examples: HCl, HNO₃, H₂SO₄.
- Weak acidExtended
- Only partially dissociated in water. Examples: ethanoic, citric and carbonic acids.
7.2 Oxides
- Acidic oxides
- Oxides of non-metals, such as SO₂ and CO₂. They react with bases and alkalis.
- Basic oxides
- Oxides of metals, such as CuO and CaO. They react with acids.
- Amphoteric oxidesExtended
- Oxides that react with both acids and bases to form a salt and water. Examples: aluminium oxide, Al₂O₃, and zinc oxide, ZnO.
7.3 Preparation of salts
- Making a soluble salt from an acid and an insoluble base (or carbonate or metal)
- Add the solid in excess to the acid, filter off the leftover solid, then crystallise the filtrate.
- When is titration used to make a salt?
- When both reactants are soluble (acid + alkali), so there is no excess solid to filter off. Repeat without the indicator to get a pure salt.
- Which common salts are always soluble?
- All sodium, potassium and ammonium salts, and all nitrates.
- Exceptions to the solubility rules for chlorides and sulfates
- Chlorides: soluble except silver and lead. Sulfates: soluble except barium, calcium and lead.
- Solubility of carbonates and hydroxides
- Mostly insoluble, except sodium, potassium and ammonium (calcium hydroxide is partially soluble).
- Hydrated and anhydrous
- Hydrated: a substance chemically combined with water (e.g. CuSO₄·5H₂O). Anhydrous: containing no water.
- Making an insoluble saltExtended
- Precipitation: mix two solutions containing its ions, then filter, wash the precipitate with distilled water and dry it.
- Water of crystallisationExtended
- The water molecules chemically combined within the crystal structure of a hydrated salt.