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AP® Chemistry · Unit 6 · Topic 6.4

Heat Capacity and Calorimetry: Topic Checklist (Chemistry 6.4)

Specific “I can…” statements for heat capacity and calorimetry, each linked to the guide section and practice question that shows whether you can really do it.

Work through the list without notes. If you cannot do a statement, follow its link, then come back. Guide = study guide; Practice = practice questions.

Understanding

  • I can explain what the sign of q means: positive when a system absorbs heat, negative when it releases heat. (Guide: “From direction to amount”)
  • I can define specific heat capacity, molar heat capacity and the heat capacity of an object, with their units. (Guide: “Molar heat capacity and the heat capacity of an object”)
  • I can explain why equal masses of different substances change temperature by different amounts when they gain the same energy. (Guide: Figure 1; Practice Q2)
  • I can state the first law of thermodynamics and use it to say that energy lost = energy gained in an insulated calorimeter. (Guide: “Calorimetry: energy lost = energy gained”)
  • I can name the three main ways a system changes its energy. (Guide: “From direction to amount”)

Calculation

  • I can calculate q with q = mcΔT, writing ΔT as final minus initial. (Guide: Worked example 1; Practice Q1)
  • I can convert a specific heat capacity into a molar heat capacity. (Practice Q3)
  • I can find an unknown specific heat capacity or a final temperature from calorimetry data. (Guide: Worked example 2; Practice Q5)
  • I can find the heat capacity of a calorimeter from a mixing experiment. (Practice Q6)
  • I can give an answer to a precision that matches the temperature change. (Guide: Worked example 2; Practice Q6(c))

Reasoning

  • I can use a temperature rise or fall in a dissolution calorimeter to decide whether dissolving is exothermic or endothermic, and give q for the process the correct sign. (Guide: Worked example 3; Practice Q4, Q7(a))
  • I can calculate the energy per mole of solute dissolved, and explain why it stays the same when the mass changes but ΔT does not. (Practice Q7(c)–(d))
  • I can state the assumptions behind a calorimetry calculation. (Guide: “The usual assumptions”; Practice Q6(d))

All ticked? Move on to Topic 6.5, Energy of Phase Changes, or return to the course roadmap.

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