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AP® Chemistry · Unit 6 · Topic 6.5

Energy of Phase Changes: Topic Checklist (Chemistry 6.5)

Specific “I can…” statements for the energy of phase changes, each linked to the guide section and practice question that shows whether you can really do it.

Work through the list without notes. If you cannot do a statement, follow its link, then come back. Guide = study guide; Practice = practice questions.

Understanding

  • I can say which phase changes increase the energy of a system and which decrease it. (Guide: “What happens to energy in a phase change”; Practice Q2)
  • I can explain why the temperature of a pure substance stays constant while it melts or boils. (Guide: “Why the temperature stays constant”; Practice Q1)
  • I can explain why ΔH_vap is larger than ΔH_fus for the same substance. (Guide; Practice Q6)
  • I can state that a phase change and its reverse have molar enthalpies of equal size and opposite sign. (Guide: “Opposite changes, opposite signs”; Practice Q6)

Calculation

  • I can calculate the energy absorbed or released in a phase change using q = n × ΔH, converting grams to moles first. (Guide: Worked example 1; Practice Q2)
  • I can compare the energy needed to change the phase of equal masses of different substances. (Practice Q3)
  • I can find a molar enthalpy of fusion or vaporization from a heating curve or heating data. (Guide: Worked example 3; Practice Q4, Q6)
  • I can combine q = mcΔT and q = n × ΔH in a calculation with several steps, keeping units consistent. (Guide: Worked example 2; Practice Q5)

Reasoning

  • I can identify each sloping and flat section of a heating or cooling curve and say what is happening to the particles. (Guide: Figure 1)
  • I can use an energy balance that includes a phase change to predict a final temperature. (Practice Q7)
  • I can explain everyday effects, such as steam burns or ice cooling a drink, using the energy of phase changes. (Practice Q5, Q7)

All ticked? Move on to Topic 6.6, Introduction to Enthalpy of Reaction, or return to the course roadmap.

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