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AP® Chemistry · Unit 9 · Topic 9.8

Galvanic (Voltaic) and Electrolytic Cells: Topic Checklist (Chemistry 9.8)

Specific “I can…” statements for galvanic and electrolytic cells, each linked to the guide section and practice question that shows whether you can really do it.

Work through the list without notes. If you cannot do a statement, follow its link, then come back. Guide = study guide; Practice = practice questions.

Understanding

  • I can explain the job of the electrodes, the half-cell solutions, the salt bridge and the voltmeter or power supply. (Guide: “What each part of a galvanic cell does”; Practice Q1)
  • I can tell a galvanic cell from an electrolytic cell using thermodynamic favourability and the direction of the energy change. (Guide: “Two kinds of electrochemical cell”; Practice Q6(d))
  • I can state that oxidation happens at the anode and reduction at the cathode in every cell. (Practice Q3, Q7)
  • I can describe what happens to atoms and ions at each electrode surface at the particle level. (Guide: “The view at the particle level”; Practice Q7(b))

Skills

  • I can identify the anode and cathode from an observation such as a mass change or a gas forming. (Guide: Worked example 1; Practice Q2, Q4)
  • I can write the half-reactions and the electron-balanced overall equation for a cell. (Practice Q4(a), Q6)
  • I can trace electron flow in the wire and ion flow in the salt bridge or molten electrolyte on a diagram. (Guide: Figures 1 and 2; Practice Q2)
  • I can link the mass changes at the two electrodes through moles of electrons. (Guide: Worked example 1; Practice Q4(b), Q6(c))
  • I can predict the products of electrolysing a molten salt and say where any gas forms. (Guide: Worked example 2; Practice Q3)

Reasoning

  • I can predict and explain how removing or changing the salt bridge, or changing an electrode, alters the cell’s behaviour. (Guide: “Changing the set-up: what happens?”; Practice Q5)
  • I can explain why reversing a galvanic cell’s reaction needs a power supply. (Practice Q6(d))
  • I can find and correct errors in someone else’s description of a cell. (Practice Q7(a))

All ticked? Move on to Topic 9.9, Cell Potential and Free Energy, or return to the course roadmap.

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